E I DUPONT DE NEMOURS & CO INC -- NASON PAINT PRODUCTS 419-64 -- -
=====================  Product Identification  =====================

Product ID:NASON PAINT PRODUCTS 419-64
MSDS Date:01/01/1999
FSC:NIIN:Submitter:N EN
Status Code:A
=== Responsible Party ===
Company Name:E I DUPONT DE NEMOURS & CO INC
Address:1007 MARKET ST
City:WILMINGTON
State:DE
ZIP:19898
Country:US
Info Phone Num:800-338-8083
Emergency Phone Num:800-441-3637
Resp. Party Other MSDS Num.:28
Chemtrec Ind/Phone:(800)424-9300
CAGE:18873
=== Contractor Identification ===
Company Name:E.I. DUPONT DE NEMOURS & CO
Address:1007 MARKET STREET
Box:City:WILMINGTON
State:DE
ZIP:19898
Country:US
Phone:800-441-7515;800-441-9442
CAGE:18873

=============  Composition/Information on Ingredients  =============

Ingred Name:BUTYL ACETATE; VP: 8.0 MM HG @ 20C
CAS:123-86-4
RTECS #:AF7350000
Other REC Limits:N/K 
OSHA PEL:710 MG/M3;150 PPM
OSHA STEL:N/K 
ACGIH TLV:713 MG/M3;150 PPM
ACGIH STEL:950 MG/M3;200 PPM
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS

Ingred Name:TOLUENE; VP: 36.7 MM HG @ 20C
CAS:108-88-3
RTECS #:XS5250000
= Wt:2.
Other REC Limits:N/K 
OSHA PEL:SEE TABLE Z-2
OSHA STEL:N/K 
ACGIH TLV:188 MG/M3;50 PPM
ACGIH STEL:N/K 
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS

Ingred Name:VM&P NAPHTHA; VP: 15 MM HG @ 37.8C	CAS# 64742-89-8
Other REC Limits:N/K 
OSHA PEL:300 PPM
OSHA STEL:400 PPM
ACGIH TLV:300 PPM
ACGIH STEL:400 PPM

Ingred Name:XYLENE; VP: 7.0 MM HG @ 25C
CAS:1330-20-7
RTECS #:ZE2100000
= Wt:2.
Other REC Limits:N/K 
OSHA PEL:100 PPM
OSHA STEL:150 PPM
ACGIH TLV:434 MG/M3;100 PPM
ACGIH STEL:651 MG/M3;150 PPM
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS

Ingred Name:MEDIUM ALIPHATIC SOLVENT NAPHTHA (PETROLEUM): (MEDIUM
    MINERAL SPIRITS); VP:10.0 MM HG @ 20C
CAS:64742-88-7

Ingred Name:ALKYD RESIN-F; VP: NONE @ 20C
CAS:66070-93-7

Ingred Name:ALKYD RESIN-G; VP: NONE @ 20C
CAS:67783-08-8

Ingred Name:TITANIUM DIOXIDE; VP: NONE @ 20C
CAS:13463-67-7
RTECS #:XR2275000
OSHA PEL:15 MG/M3
ACGIH TLV:10 MG/M3

=====================  Hazards Identification  =====================

Routes of Entry: Inhalation:YES  Skin:YES  Ingestion:YES
Reports of Carcinogenicity:NTP:NO    IARC:NO	OSHA:NO
Health Hazards Acute and Chronic:GEN EFTS: INGEST: GI DISTRESS. INHAL:
    MAY CAUSE NOSE & THROAT IRRIT. RPTD & PRLNG OVEREXP TO SOLVS MAY
    LEAD TO PERM BRAIN & NERV SYS DMG. EYE WATERING, HDCH, NAUS, DIZZ &
    LOSS OF COORD ARE SIGNS THAT  SOLV LEVELS ARE TOO HIGH. ADDNL EFTS
    WHEN THIS MATL CONTAINS/IS MIXED W/ISOCYANATE ACTIVATOR/HARDENER:
    EXPOS TO ISOCYANATES MAY CAUSE RESP SENSIT. THIS EFT MAY BE PERM.
    THIS EFT MAY BE DELAYED FOR SEV ERAL HRS AFTER EXPOS. RPTD OVEREXP
    TO ISOCYANATES MAY CAUSE DECR IN LUNG FUNC WHICH MAY BE PERM. EYES:
    MAY CAUSE IRRIT/BURNING. SKIN: RPTD/PRLNG LIQ CONT MAY CAUSE IRRIT
    W/DISCOMFORT & DERM. (EFTS OF  OVEREXP)
Effects of Overexposure:HEALTH HAZ: TOLUENE APPEARS ON THE NAVY
    OCCUPATIONAL CHEMICAL REPRODUCTIVE HAZARDS LIST. CONSULT
    APPROPRIATE HEALTH PROFESSIONALS CONCERNING LATEST HAZARD LIST
    INFORMATION & SAFE HANDLING & EXPOSURE I NFORMATION .  SPECIFIC
    EFFECTS: VM & P NAPHTHA/ MEDIUM MINERAL SPIRITS: LABORATORY STUDIES
    WITH RATS HAVE SHOWN THAT PETROLEUM DISTILLATES CAN CAUSE KIDNEY
    DAMAGE & KIDNEY OR LIVER TUMORS. THESE  EFFECTS WERE NOT SEEN IN
    SIMILAR STUDIES WITH GUINEA PIGS, (TOXICOLOGICAL INFO)
Medical Cond Aggravated by Exposure:INDIVIDUALS W/BRTHG PROBLEMS/PRIOR
    RXN TO ISOCYANATES MUST NOT BE EXPOSED TO VAPS/SPRAY MISTS OF THIS
    PROD. INDIVIDUALS W/PREEXISTING DISEASES OF CNS, LUNGS,
    LIVER/KIDNEYS MAY HAVE INCRD (SARA REGS)

=======================  First Aid Measures  =======================

First Aid:INGESTION: IN THE UNLIKELY EVENT OF INGESTION, CALL A
    PHYSICIAN IMMEDIATELY AND HAVE THE NAMES OF THE INGREDIENTS
    AVAILABLE. DO NOT INDUCE VOMITING. INHALATION: IF AFFECTED BY
    INHALATION OF VAPOR OR S PRAY MIST, REMOVE TO FRESH AIR. IF
    BREATHING DIFFICULTY PERSISTS OR OCCURS LATER, CONSULT A PHYSICIAN.
    EYES: IN CASE EYE CONTACT, IMMEDIATELY FLUSH WITH PLENTY OF WATER
    FOR AT LEAST 15 MINUTES; CALL A  PHYSICIAN. SKIN: WASH WITH SOAP
    AND WATER. IF IRRITATION OCCURS, CONTACT A PHYSICIAN.

=====================  Fire Fighting Measures  =====================

Flash Point Method:CC
Flash Point:>-6.7C, 20.F
20F - 73F
Lower Limits:0.7%
Upper Limits:23.0%
Extinguishing Media:UNIVERSAL AQUEOUS FILM-FORMING FOAM, CARBON
    DIOXIDE, DRY CHEMICAL.
Fire Fighting Procedures:WEAR NIOSH APPROVED SCBA AND FULL PROTECTIVE
    EQUIPMENT . WATER FROM FOG NOZZLES MAY BE USED TO COOL CLOSED
    CONTAINERS TO PREVENT PRESSURE BUILD-UP.
Unusual Fire/Explosion Hazard:WHEN HEATED ABOVE THE FLASH POINT, EMITS
    FLAMMABLE VAPORS WHICH, WHEN MIXED WITH AIR, CAN BURN OR BE
    EXPLOSIVE. FINE MISTS OR SPRAYS MAY BE FLAMMABLE AT TEMPERATURES
    BELOW THE FLASH POINT.

==================  Accidental Release Measures  ==================

Spill Release Procedures:VENT AREA. REMOVE IGNIT SOURCES. PVNT SKIN &
    EYE CONT & BRTHG OF VAP. WEAR NIOSH APPRVD RESP, EYE PROT, GLOVES &
    PROT CLTHG. CONFINE & REMOVE W/INERT ABSORB. IF MATL CONTAINS/IS
    MIXED W/ISOCYANATE ACT IVATOR/HARDENER: WEAR POS-PRESS, SUPP-AIR
    RESP (NIOSH APPRVD TC-19C). POUR LIQ DECONTAM SOLN OVER SPILL &
    ALLOW TO SIT AT LEAST 10 MINS. TYPICAL DECONTAM SOLNS FOR
    ISOCYANATES-CONTAINING (FED REGS)

======================	Handling and Storage  ======================

Handling and Storage Precautions:OBSERVE LABEL PRECAUTIONS. KEEP AWAY
    FROM HEAT, SPARKS AND FLAME. CLOSE CONTAINER AFTER EACH USE. GROUND
    CONTAINERS WHEN POURING. DO NOT STORE ABOVE 120F. OSHA STORAGE: IB.
Other Precautions:DO NOT SAND, FLAME CUT, BRAZE OR WELD DRY COATING
    WITHOUT A NIOSH APPROVED RESPIRATOR OR APPROPRIATE VENTILATION.

=============  Exposure Controls/Personal Protection  =============

Respiratory Protection:DO NOT BREATHE VAPS/MISTS. WHEN PRODS ARE USED
    W/PAINTS REQUIRING ISOCYANATE ACTIVATORS/HARDENERS, WEAR POS-PRESS,
    SUPP-AIR RESP (NIOSH APPRVD TC-19C) WHILE MIXING ACTIVATOR/HARDENER
    W/PAINT, DURING A PPLICATION & UNTIL ALL VAPS & SPRAY MISTS ARE
    EXHAUSTED. IF PROD IS USED W/OUT ISOCYANATE ACTIVATORS/HARDENERS, A
    PROPERLY FITTED AIR-PURIFYING (STATE REGS)
Ventilation:PROVIDE SUFFICIENT VENTILATION IN VOLUME AND PATTERN TO
    KEEP CONTAMINANTS BELOW APPLICABLE EXPOSURE LIMITS.
Protective Gloves:NEOPRENE GLOVES ARE RECOMMENDED.
Eye Protection:ANSI APPROVED CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:ANSI APPROVED EMERGENCY EYEWASH AND DELUGE
    SHOWER . COVERALLS ARE RECOMMENDED.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING AND BEFORE
    EATING OR SMOKING.
Supplemental Safety and Health
PHYSICAL/CHEM PROPERTIES: GAL WT (#/GAL): 6.66-13.03; WT % VOLAT:
    9.68%-100%; GAL WT:8.31; WT PCT SOLIDS:46.09; VOL PCT SOLIDS:
    31.38; SOLV DENSITY:6.53; VOC LE: 4.5; VOC AP: 4.5.

==================  Physical/Chemical Properties  ==================

Boiling Pt:>26.C, 78.8F
B.P. Text:26C - 900C
Vapor Pres:SEE INGREDIENTS
Vapor Density:HVR/AIR
Evaporation Rate & Reference:LESS THAN ETHER
Solubility in Water:MISCIBLE
Percent Volatiles by Volume:12.5% - 100%

=================  Stability and Reactivity Data  =================

Stability Indicator/Materials to Avoid:YES
NONE REASONABLY FORESEEABLE.
Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE,
    SMOKE, OXIDES OF HEAVY METALS IN INGREDIENTS SECTION.

===================  Toxicological Information	===================

Toxicological Information:OVEREXPOSURE: DOGS OR MONKEYS. SEVERAL
    STUDIES EVALUATING PETROLEUM WORKERS HAVE NOT SHOWN A SIGNIFICANT
    INCREASE OF KIDNEY DMG OR AN INCREASE IN KIDNEY OR LIVER TUMORS.
    TOLUENE:  RECURRENT OVEREXP MA Y RESULT IN LIVER & KIDNEY INJURY.
    HIGH AIRBORNE LEVELS HAVE PRODUCED IRREG HEARTBEATS IN ANIMALS &
    OCCASIONAL PALPITATIONS IN HUMANS. RATS EXPOSED TO VERY HIGH
    AIRBORNE LEVELS HAVE EXHIBITED HIGH FRE Q HEARING DEFICITS.
    SIGNIFICANCE OF THIS TO MAN IS UNKNOWN. CHROMOSOMAL CHANGES IN
    CIRCULATING BLOOD OF EXPOSED WORKERS HAVE BEEN REPORTED.
    SIGNIFICANCE OF THESE RPTS IS UNCLEAR BECAUSE OF EXPOS TO OT HER
    SUBSTANCES. (ECOLOGICAL INFO)

=====================  Ecological Information  =====================

Ecological:TOX INFO: XYLENE: RECURRENT OVEREXPOSURE MAY RESULT IN LIVER
    & KIDNEY INUURY.  CAN BE ABSORBED THROUGH SKIN IN HARMFUL AMOUNTS.
    INDIVIDUALS W/PRE-EXISTING DISEASE OF THE CENTRAL NERVOUS SYSTEM,
    KIDNEY S, LIVER, CARDIOVASCULAR SYSTEM, LUNGS OR BONE MARROW MAY
    HAVE INCREASED SUSCEPTIBILITY TO THE TOXICITY OF EXCESSIVE
    EXPOSURES. CANADA CLASSIFIES XYLENE AS A DEVELOPMENTAL TOXIN AS
    HIGH EXPOSURES TO X YLENES IN SOME ANIMAL STUDIES HAVE BEEN
    REPORTED TO CAUSE HEALTH EFFECTS ON THE DEVELOPING FETUS/EMBRYO.
    THESE EFFECTS WERE OFTEN AT LEVELS TOXIC TO THE ADULT ANIMAL. THE
    SIGNIFICANCE OF THESE EFFECTS  TO HUMANS IS NOT KNOWN. (OTHER INFO)

====================  Disposal Considerations  ====================

Waste Disposal Methods:DO NOT ALLOW MATERIAL TO CONTAMINATE GROUND
    WATER SYSTEMS. INCINERATE ABSORBED MATERIAL IN ACCORDANCE WITH
    FEDERAL, STATE, AND LOCAL REQUIREMENTS. DO NOT INCINERATE IN CLOSED
    CONTAINERS.

=====================  Regulatory Information  =====================

SARA Title III Information:THE FOLLOWING CHEMICALS ARE SUBJECT TO
    REPORTING REQUIREMENTS OF SECTION 313 OF EMERGENCY PLANNING &
    RIGHT-TO-KNOW ACT OF 1986 & OF 40 CFR 372:	 TOLUENE & XYLENE.
    MEDICAL CONDITIONS: SUSCEPTIBILITY T O TOXICITY OF EXCESS EXPOSURE.
    INDIVIDUALS WITH PREEXISTING DISEASES OF KIDNEYS, LIVER,
    CARDIOVASCULAR SYSTEM BONE MARROW MAY HAVE INCREASED SUSCEPTIBILITY
    TO TOXICITY OF EXCESS EXPOSURE.
Federal Regulatory Information:SPILL PROC: MATERIALS ARE: 20%
    SURFACTANT (TERGITOL TMN 10) & 80% WATER OR 0-10% AMMONIA, 2-5%
    DETERGENT & WATER (BALANCE). PRESS CAN BE GENERATED.  DO NOT SEAL
    CONTAINER. AFTER 48 HOURS, MATERIAL MAY  BE SEALED & DISPOSED OF
    PROPERLY. IF MATERIAL DOES NOT CONTAIN/IS NOT MIXED WITH ISOCYANATE
    ACTIVATOR/HARDENER: WEAR PROPERLY FITTED AIR-PURIFYING RESP WITH
    ORGANIC VAPOR CARTRIDGES (NIOSH APPRVD TC- 23C).
State Regulatory Information:WARNING: TOLUENE IS KNOWN TO THE STATE OF
    CALIFORNIA TO CAUSE BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM. RESP
    PROT: RESPIRATOR W/ORGANIC VAPOR CARTRIDGES (NIOSH TC-23C) &
    PARTICULATE FILTER (NIOSH TC-8 4A) MAY BE USED. FOLLOW RESP MFR'S
    DIRECTIONS FOR RESP USE. DO NOT PERMIT ANYONE W/OUT PROTECTION IN
    PAINTING AREA. REFER TO HARDENER/ACTIVATOR LABEL INSTRUCTIONS &
    MSDS FOR FURTHER INFORMATION. PERSO NS WITH HISTORY OF
    LUNG/BREATHING PROBLEMS/PRIOR REACTION TO ISOCYANATES SHOULD NOT
    USE/BE EXPOSED T O PRODUCT IF MIXED WITH ISOCYANATE
    ACTIVATORS/HARDENERS.

=======================  Other Information  =======================

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